3-Methyl-4,5-di­hydro­oxazolium tetra­phenyl­borate

نویسندگان

  • Ioannis Tiritiris
  • Stefan Saur
  • Willi Kantlehner
چکیده

In the cation of the title salt, C4H8NO(+)·C24H20B(-), the C-N bond lengths are 1.272 (2), 1.4557 (19) and 1.4638 (19) Å, indicating double- and single-bond character, respectively. The C-O bond length of 1.3098 (19) Å shows that double-bond character and charge delocalization occurs within the NCO plane of the cation. In the crystal, a C-H⋯π inter-action is present between the methyl-ene H atom of the cation and one phenyl ring of the tetra-phenyl-borate ion. The latter forms an aromatic pocket in which the cation is embedded.

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عنوان ژورنال:

دوره 70  شماره 

صفحات  -

تاریخ انتشار 2014